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Iron-Catalyzed Asymmetric Epoxidation of β,β-Disubstituted Enones
The combination of Fe(OTf)(2) and novel phenanthroline ligands enables the catalytic asymmetric epoxidation of acyclic β,β-disubstituted enones which have been heretofore inaccessible substrate classes. The reactions provide highly enantioenriched α,β-epoxyketones (up to 92% ee) which are further co...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2011
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3116448/ https://ncbi.nlm.nih.gov/pubmed/21553923 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja201873d |
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