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Water-Soluble Fe(II)−H(2)O Complex with a Weak O−H Bond Transfers a Hydrogen Atom via an Observable Monomeric Fe(III)−OH
[Image: see text] Understanding the metal ion properties that favor O−H bond formation versus cleavage should facilitate the development of catalysts tailored to promote a specific reaction, e.g., C−H activation or H(2)O oxidation. The first step in H(2)O oxidation involves the endothermic cleavage...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4485620/ https://ncbi.nlm.nih.gov/pubmed/25611075 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5068405 |
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