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C–H Functionalization of Cyclic Amines: Redox-Annulations with α,β-Unsaturated Carbonyl Compounds

Cyclic amines such as pyrrolidine and 1,2,3,4-tetrahydroisoquinoline undergo redox-annulations with α,β-unsaturated aldehydes and ketones. Carboxylic acid promoted generation of a conjugated azomethine ylide is followed by 6π-electrocylization, and, in some cases, tautomerization. The resulting ring...

詳細記述

保存先:
書誌詳細
出版年:Chem Commun (Camb)
主要な著者: Kang, YoungKu, Richers, Matthew T., Sawicki, Conrad H., Seidel, Daniel
フォーマット: Artigo
言語:Inglês
出版事項: 2015
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC4477284/
https://ncbi.nlm.nih.gov/pubmed/26051897
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cc03390j
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