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Computational studies of electronic circular dichroism spectra predict absolute configuration assignments for the guanine oxidation product 5-carboxamido-5-formamido-2-iminohydantoin()
Oxidation of the guanine heterocycle by two electrons can yield the chiral product 5-carboxamido-5-formamido-2-iminohydantoin (2Ih). The 2Ih free base enantiomers were synthesized from 2′-deoxyguanosine oxidized with a Cu(II)/H(2)O(2) oxidant system followed by hydrolysis of the N-glycosidic bond. T...
שמור ב:
| הוצא לאור ב: | Tetrahedron Lett |
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| Main Authors: | , , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2014
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4472374/ https://ncbi.nlm.nih.gov/pubmed/26097262 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2014.12.052 |
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