טוען...
Temperature dependence of turnover in a Sc(OTf)(3)-catalyzed intramolecular Schmidt reaction
The intramolecular Schmidt reaction of ketones and tethered azides is an efficient method for the generation of amides and lactams. This reaction is catalyzed by Lewis acids, which tightly bind the strongly basic amide product and result in product inhibition. We report herein conditions to achieve...
שמור ב:
| הוצא לאור ב: | Tetrahedron Lett |
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| Main Authors: | , , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2015
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4465195/ https://ncbi.nlm.nih.gov/pubmed/26085693 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2014.12.068 |
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