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Multivalent polyglycerol supported imidazolidin-4-one organocatalysts for enantioselective Friedel–Crafts alkylations

The first immobilization of a MacMillan’s first generation organocatalyst onto dendritic support is described. A modified tyrosine-based imidazolidin-4-one was grafted to a soluble high-loading hyperbranched polyglycerol via a copper-catalyzed alkyne–azide cycloaddition (CuAAC) reaction and readily...

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Bibliografische gegevens
Gepubliceerd in:Beilstein J Org Chem
Hoofdauteurs: Pecchioli, Tommaso, Muthyala, Manoj Kumar, Haag, Rainer, Christmann, Mathias
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Beilstein-Institut 2015
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4463494/
https://ncbi.nlm.nih.gov/pubmed/26150897
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.83
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