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Chemical reaction mechanisms in solution from brute force computational Arrhenius plots
Decomposition of activation free energies of chemical reactions, into enthalpic and entropic components, can provide invaluable signatures of mechanistic pathways both in solution and in enzymes. Owing to the large number of degrees of freedom involved in such condensed-phase reactions, the extensiv...
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| Udgivet i: | Nat Commun |
|---|---|
| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Nature Pub. Group
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4458863/ https://ncbi.nlm.nih.gov/pubmed/26028237 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms8293 |
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