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On the curvature in logarithmic plots of rate coefficients for chemical reactions

In terms of the reduced potential energy barrier ζ = Δu(TS)/kT, the rate coefficients for chemical reactions are usually expressed as proportional to e(-ζ). The coupling between vibrational modes of the medium to the reaction coordinate leads to a proportionality of the regularized gamma function of...

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Autor principal: Canepa, Carlo
Format: Artigo
Idioma:Inglês
Publicat: BioMed Central 2011
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3117758/
https://ncbi.nlm.nih.gov/pubmed/21545752
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1186/1752-153X-5-22
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