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On the curvature in logarithmic plots of rate coefficients for chemical reactions
In terms of the reduced potential energy barrier ζ = Δu(TS)/kT, the rate coefficients for chemical reactions are usually expressed as proportional to e(-ζ). The coupling between vibrational modes of the medium to the reaction coordinate leads to a proportionality of the regularized gamma function of...
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| Formato: | Artigo |
| Idioma: | Inglês |
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BioMed Central
2011
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| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3117758/ https://ncbi.nlm.nih.gov/pubmed/21545752 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1186/1752-153X-5-22 |
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