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Convex Arrhenius plots and their interpretation

This paper draws attention to selected experiments on enzyme-catalyzed reactions that show convex Arrhenius plots, which are very rare, and points out that Tolman's interpretation of the activation energy places a fundamental model-independent constraint on any detailed explanation of these rea...

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Detalhes bibliográficos
Main Authors: Truhlar, Donald G., Kohen, Amnon
Formato: Artigo
Idioma:Inglês
Publicado em: The National Academy of Sciences 2001
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC14672/
https://ncbi.nlm.nih.gov/pubmed/11158559
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