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Methoxy-Directed Aryl-to-Aryl 1,3-Rhodium Migration
Through-space metal/hydrogen shift is an important strategy for transition metal-catalyzed C-H bond activation. Here we describe the synthesis and characterization of a Rh(I) 2,6-dimethoxybenzoate complex that underwent stoichiometric rearrangement via a highly unusual 1,3- rhodium migration. This a...
Shranjeno v:
| izdano v: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2013
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4447322/ https://ncbi.nlm.nih.gov/pubmed/24171626 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja409049t |
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