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Atropurpuran – Missing Biosynthetic Link Leading to the Hetidine and Arcutine C(20)-Diterpenoid Alkaloids or an Oxidative Degradation Product?

A possible biosynthetic link between atropurpuran, the hetidine diterpenoid alkaloids and the alkaloid arcutine and congeners is proposed. The feasibility of aspects of this biosynthesis, especially key 1,2-rearrangements, have been examined computationally.

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Bibliografiska uppgifter
I publikationen:Tetrahedron Lett
Huvudupphovsmän: Weber, Manuel, Owens, Kyle, Sarpong, Richmond
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2015
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4445844/
https://ncbi.nlm.nih.gov/pubmed/26028789
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2015.01.111
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