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Infrared identification of the Criegee intermediates syn- and anti-CH(3)CHOO, and their distinct conformation-dependent reactivity
The Criegee intermediates are carbonyl oxides that play critical roles in ozonolysis of alkenes in the atmosphere. So far, the mid-infrared spectrum of only the simplest Criegee intermediate CH(2)OO has been reported. Methyl substitution of CH(2)OO produces two conformers of CH(3)CHOO and consequent...
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| Izdano u: | Nat Commun |
|---|---|
| Glavni autori: | , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Nature Pub. Group
2015
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4432623/ https://ncbi.nlm.nih.gov/pubmed/25959902 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms8012 |
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