Observation of the simplest Criegee intermediate CH(2)OO in the gas-phase ozonolysis of ethylene

Ozonolysis is one of the dominant oxidation pathways for tropospheric alkenes. Although numerous studies have confirmed a 1,3-cycloaddition mechanism that generates a Criegee intermediate (CI) with form R(1)R(2)COO, no small CIs have ever been directly observed in the ozonolysis of alkenes because o...

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Bibliographic Details
Published in:Sci Adv
Main Authors: Womack, Caroline C., Martin-Drumel, Marie-Aline, Brown, Gordon G., Field, Robert W., McCarthy, Michael C.
Format: Artigo
Language:Inglês
Published: American Association for the Advancement of Science 2015
Subjects:
Research Articles
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4643816/
https://ncbi.nlm.nih.gov/pubmed/26601145
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/sciadv.1400105
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