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Observation of the simplest Criegee intermediate CH(2)OO in the gas-phase ozonolysis of ethylene
Ozonolysis is one of the dominant oxidation pathways for tropospheric alkenes. Although numerous studies have confirmed a 1,3-cycloaddition mechanism that generates a Criegee intermediate (CI) with form R(1)R(2)COO, no small CIs have ever been directly observed in the ozonolysis of alkenes because o...
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| Publicado no: | Sci Adv |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Association for the Advancement of Science
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4643816/ https://ncbi.nlm.nih.gov/pubmed/26601145 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/sciadv.1400105 |
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