Cargando...
γ, δ, ε-C(sp(3))–H Functionalization through A Directed Radical H-Abstraction
Aliphatic amides are selectively functionalized at the γ and δ–positions through a directed radical 1,5 and 1,6-H-abstraction. The initially formed γ- or δ-lactams are intercepted by NIS and TMSN(3) leading to multiple C–H functionalizations at the γ, δ, and ε–positions. This new reactivity is explo...
Gardado en:
| Publicado en: | J Am Chem Soc |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2015
|
| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4431913/ https://ncbi.nlm.nih.gov/pubmed/25915558 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b02065 |
| Tags: |
Engadir etiqueta
Sen Etiquetas, Sexa o primeiro en etiquetar este rexistro!
|