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Excited State Investigation of a New Ru(II) Complex for Dual Reactivity with Low Energy Light
The new complex [Ru(tpy)(Me(2)dppn)(py)](2+) efficiently photodissociates py in CH(3)CN with Φ(500) = 0.053(1) induced by steric bulk from methyl substituents and produces (1)O(2) with Φ(Δ) = 0.69(9) from its long-lived (3)ππ* excited state. The unique excited state processes that result in dual rea...
में बचाया:
| में प्रकाशित: | Chem Commun (Camb) |
|---|---|
| मुख्य लेखकों: | , , |
| स्वरूप: | Artigo |
| भाषा: | Inglês |
| प्रकाशित: |
2015
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| विषय: | |
| ऑनलाइन पहुंच: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4430371/ https://ncbi.nlm.nih.gov/pubmed/25912170 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cc01865j |
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