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Excited State Investigation of a New Ru(II) Complex for Dual Reactivity with Low Energy Light

The new complex [Ru(tpy)(Me(2)dppn)(py)](2+) efficiently photodissociates py in CH(3)CN with Φ(500) = 0.053(1) induced by steric bulk from methyl substituents and produces (1)O(2) with Φ(Δ) = 0.69(9) from its long-lived (3)ππ* excited state. The unique excited state processes that result in dual rea...

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Detalhes bibliográficos
Publicado no:Chem Commun (Camb)
Main Authors: Knoll, J. D., Albani, B. A., Turro, C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4430371/
https://ncbi.nlm.nih.gov/pubmed/25912170
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cc01865j
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