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Unusual Role of Excited State Mixing in the Enhancement of Photoinduced Ligand Exchange in Ru(II) Complexes

Four Ru(II) complexes were prepared bearing two new tetradentate ligands, cyTPA and 1-isocyTPQA, which feature a piperidine ring that provides a structurally rigid backbone and facilitates the installation of other donors as the fourth chelating arm, while avoiding the formation of stereoisomers. Th...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Loftus, Lauren M., Li, Ao, Fillman, Kathlyn L., Martin, Philip D., Kodanko, Jeremy J., Turro, Claudia
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5901749/
https://ncbi.nlm.nih.gov/pubmed/29226680
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b09937
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