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Combining Solvent Isotope Effects with Substrate Isotope Effects in Mechanistic Studies of Alcohol and Amine Oxidation by Enzymes

Oxidation of alcohols and amines is catalyzed by multiple families of flavin-and pyridine nucleotide-dependent enzymes. Measurement of solvent isotope effects provides a unique mechanistic probe of the timing of the cleavage of the OH and NH bonds, necessary information for a complete description of...

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Pubblicato in:Biochim Biophys Acta
Autore principale: Fitzpatrick, Paul F.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2014
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4416078/
https://ncbi.nlm.nih.gov/pubmed/25448013
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bbapap.2014.10.020
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