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Virtually Instantaneous, Room-temperature [(11)C]-Cyanation Using Biaryl Phosphine Pd(0) Complexes
A new radiosynthetic protocol for the preparation of [(11)C]aryl nitriles has been developed. This process is based on the direct reaction of in situ prepared L•Pd(Ar)X complexes (L=biaryl phosphine) with [(11)C]HCN. The strategy is operationally simple, exhibits a remarkably wide substrate scope wi...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4394387/ https://ncbi.nlm.nih.gov/pubmed/25565277 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja512115s |
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