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Structure and Reactivity of [(L•Pd)(n)•(1,5-cyclooctadiene)] (n=1–2) Complexes Bearing Biaryl Phosphine Ligands

The structure of the stable Pd(0) precatalyst [(1,5-cyclooctadiene)(L•Pd)(2)] (L = AdBrettPhos) for the Pd-catalyzed fluorination of aryl triflates has been further studied by solid state NMR and X-ray cystrallography of the analogous N-phenylmaleimide complex. The reactivity of this complex with CD...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Lee, Hong Geun, Milner, Phillip J., Colvin, Michael T., Andreas, Loren, Buchwald, Stephen L.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2014
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4206912/
https://ncbi.nlm.nih.gov/pubmed/25346547
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ica.2014.06.008
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