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Palladium-Catalyzed Intramolecular C–H Difluoroalkyation: The Synthesis of Substituted 3,3-Difluoro-2-oxindoles()

The synthesis of 3,3-difluoro-2-oxindoles through a robust and efficient palladium-catalyzed C–H difluoroalkylation is described. This process generates a broad range of difluorooxindoles from readily prepared starting materials. The use of BrettPhos as the ligand was crucial for high efficiency. Pr...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Shi, Shi-Liang, Buchwald, Stephen L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4384468/
https://ncbi.nlm.nih.gov/pubmed/25476241
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201410471
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