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Solution-Phase Perfluoroalkylation of C(60) Leads to Efficient and Selective Synthesis of Bis-Perfluoroalkylated Fullerenes

A solution-phase perfluoroalkylation of C(60) with a series of R(F)I reagents was studied. The effects of molar ratio of the reagents, reaction time, and presence of copper metal promoter on fullerene conversion and product composition were evaluated. Ten aliphatic and aromatic R(F)I reagents were i...

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Bibliographische Detailangaben
Veröffentlicht in:J Fluor Chem
Hauptverfasser: Kuvychko, Igor V., Strauss, Steven H., Boltalina, Olga V.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2012
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4384446/
https://ncbi.nlm.nih.gov/pubmed/25843973
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jfluchem.2012.04.014
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