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Solution-Phase Perfluoroalkylation of C(60) Leads to Efficient and Selective Synthesis of Bis-Perfluoroalkylated Fullerenes

A solution-phase perfluoroalkylation of C(60) with a series of R(F)I reagents was studied. The effects of molar ratio of the reagents, reaction time, and presence of copper metal promoter on fullerene conversion and product composition were evaluated. Ten aliphatic and aromatic R(F)I reagents were i...

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Vydáno v:J Fluor Chem
Hlavní autoři: Kuvychko, Igor V., Strauss, Steven H., Boltalina, Olga V.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4384446/
https://ncbi.nlm.nih.gov/pubmed/25843973
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jfluchem.2012.04.014
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