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Solution-Phase Perfluoroalkylation of C(60) Leads to Efficient and Selective Synthesis of Bis-Perfluoroalkylated Fullerenes

A solution-phase perfluoroalkylation of C(60) with a series of R(F)I reagents was studied. The effects of molar ratio of the reagents, reaction time, and presence of copper metal promoter on fullerene conversion and product composition were evaluated. Ten aliphatic and aromatic R(F)I reagents were i...

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Detalhes bibliográficos
Publicado no:J Fluor Chem
Main Authors: Kuvychko, Igor V., Strauss, Steven H., Boltalina, Olga V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4384446/
https://ncbi.nlm.nih.gov/pubmed/25843973
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jfluchem.2012.04.014
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