Reversible Mechanical Switching of Magnetic Interactions in a Molecular Shuttle

An acid–base switchable molecular shuttle based on a [2]rotaxane, incorporating stable radical units in both the ring and dumbbell components, is reported. The [2]rotaxane comprises a dibenzo[24]crown-8 ring (DB24C8) interlocked with a dumbbell component that possesses a dialkylammonium (NH(2)(+)) a...

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Bibliographic Details
Published in:ChemistryOpen
Main Authors: Bleve, Valentina, Schäfer, Christian, Franchi, Paola, Silvi, Serena, Mezzina, Elisabetta, Credi, Alberto, Lucarini, Marco
Format: Artigo
Language:Inglês
Published: BlackWell Publishing Ltd 2015
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4380948/
https://ncbi.nlm.nih.gov/pubmed/25861565
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201402073
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