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Chemical On/Off Switching of Mechanically Planar Chirality and Chiral Anion Recognition in a [2]Rotaxane Molecular Shuttle

[Image: see text] We exploit a reversible acid–base triggered molecular shuttling process to switch an appropriately designed rotaxane between prochiral and mechanically planar chiral forms. The mechanically planar enantiomers and their interconversion, arising from ring shuttling, have been charact...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Corra, Stefano, de Vet, Christiaan, Groppi, Jessica, La Rosa, Marcello, Silvi, Serena, Baroncini, Massimo, Credi, Alberto
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2019
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6693800/
https://ncbi.nlm.nih.gov/pubmed/31129959
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b00941
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