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Enantioselective Cascade Cyclization/Protodemetalation of Polyenes with N(3)Pt(2+) Catalysts
[Image: see text] The combination of the N-based pincer ligand PyBOX with Pt(2+) leads to new catalysts for the enantioselective cycloisomerization of dienyl- and trienyl-ols. The mechanistic combination of electrophilic cyclization followed by rapid protodemetalation is surprising and leads to a po...
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| Publicat a: | ACS Catal |
|---|---|
| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American
Chemical Society
2014
|
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4372115/ https://ncbi.nlm.nih.gov/pubmed/25838970 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cs401190c |
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