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Reversibility Effects on the Stereoselectivity of Pt(II)-Mediated Cascade Poly-ene Cyclizations
Cyclization of 1,5-dienes bearing nucleophilic traps with electrophilic trisphosphine pincer ligated Pt(II) complexes results in the formation of a polycyclic Pt-alkyl via an Pt(η(2)-alkene) intermediate. With electron rich triphosphine ligands an equilibrium between the Pt(η(2)-alkene) and Pt-alkyl...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2007
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2586057/ https://ncbi.nlm.nih.gov/pubmed/18095679 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja075518i |
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