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Reversibility Effects on the Stereoselectivity of Pt(II)-Mediated Cascade Poly-ene Cyclizations

Cyclization of 1,5-dienes bearing nucleophilic traps with electrophilic trisphosphine pincer ligated Pt(II) complexes results in the formation of a polycyclic Pt-alkyl via an Pt(η(2)-alkene) intermediate. With electron rich triphosphine ligands an equilibrium between the Pt(η(2)-alkene) and Pt-alkyl...

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Bibliographic Details
Main Authors: Feducia, Jeremiah A., Gagné, Michel R.
Format: Artigo
Language:Inglês
Published: 2007
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2586057/
https://ncbi.nlm.nih.gov/pubmed/18095679
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja075518i
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