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Gold(I)-Catalyzed Cascade Cyclization of Allenyl Epoxides

[Image: see text] Cationic gold(I) phosphite catalysts activate allenes for epoxide cascade reactions. The system is tolerant of numerous functional groups (sulfones, esters, ethers, sulfonamides) and proceeds at room temperature in dichloromethane. The cyclization pathway is sensitive to the substi...

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Autors principals: Tarselli, Michael A., Lucas Zuccarello, J, Lee, Stephen J., Gagné, Michel R.
Format: Artigo
Idioma:Inglês
Publicat: 2009
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2742359/
https://ncbi.nlm.nih.gov/pubmed/19588972
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901391s
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