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Probing Bis-Fe(IV) MauG: Experimental Evidence for the Long-Range Charge-Resonance Model
The biosynthesis of tryptophan tryptophylquinone, a protein-derived cofactor, involves a long-range reaction mediated by a bis-Fe(IV) intermediate of a di-heme enzyme, MauG. Recently, a unique charge-resonance (CR) phenomenon was discovered in this intermediate, and a biological, long-distance CR mo...
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| Izdano u: | Angew Chem Int Ed Engl |
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| Glavni autori: | , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2015
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4363735/ https://ncbi.nlm.nih.gov/pubmed/25631460 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201410247 |
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