Synthesis and Characterization of an f-Block Terminal Parent Imido [U=NH] Complex: A Masked Uranium(IV) Nitride

[Image: see text] Deprotonation of [U(Tren(TIPS))(NH(2))] (1) [Tren(TIPS) = N(CH(2)CH(2)NSiPr(i)(3))(3)] with organoalkali metal reagents MR (M = Li, R = Bu(t); M = Na–Cs, R = CH(2)C(6)H(5)) afforded the imido-bridged dimers [{U(Tren(TIPS))(μ-N[H]M)}(2)] [M = Li–Cs (2a–e)]. Treatment of 2c (M = K) w...

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Publicado en:J Am Chem Soc
Autores principales: King, David M., McMaster, Jonathan, Tuna, Floriana, McInnes, Eric J. L., Lewis, William, Blake, Alexander J., Liddle, Stephen T.
Formato: Artigo
Lenguaje:Inglês
Publicado: American Chemical Society 2014
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4353020/
https://ncbi.nlm.nih.gov/pubmed/24697157
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja502405e
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