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Development and investigation of a site selective palladium-catalyzed 1,4-difunctionalization of isoprene using pyridine–oxazoline ligands

Palladium-catalyzed 1,4-difunctionalizations of isoprene that produce skipped polyenes are reported. Complex isomeric product mixtures are possible as a result of the difficult-to-control migratory insertion of isoprene into a Pd–alkenyl bond, but good site selectivity has been achieved using easily...

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Xehetasun bibliografikoak
Argitaratua izan da:Chem Sci
Egile Nagusiak: McCammant, Matthew S., Sigman, Matthew S.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Royal Society of Chemistry 2015
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4334162/
https://ncbi.nlm.nih.gov/pubmed/25705367
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03074e
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