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Mechanism and Selectivity in the Pd-Catalyzed Difunctionalization of Isoprene
The three-component coupling of isoprene, an alkenyl triflate and styrenylboronic acid catalyzed by a palladium pyrox complex access to skipped dienes from simple chemical feedstocks. Unfortunately, the transformation proceeds with only moderate selectivity and yields. The reaction mechanism and fac...
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| Publicado en: | J Org Chem |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2016
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5316510/ https://ncbi.nlm.nih.gov/pubmed/27486829 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b01317 |
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