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Palladium-Catalyzed 1,3-Difunctionalization using Terminal Alkenes with Alkenyl Nonaflates and Aryl Boronic Acids

A Pd-catalyzed 1,3-difunctionalization of terminal alkenes using 1,1-disubstituted alkenyl nonaflates and arylboronic acid coupling partners is reported. This transformation affords allylic arene products that are difficult to selectively access using traditional Heck cross-coupling methodologies. T...

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Pubblicato in:Org Lett
Autori principali: McCammant, Matthew S., Shigeta, Takashi, Sigman, Matthew S.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2016
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5053098/
https://ncbi.nlm.nih.gov/pubmed/27019228
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b00517
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