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Nuclear resonance vibrational spectroscopy reveals the FeS cluster composition and active site vibrational properties of an O(2)-tolerant NAD(+)-reducing [NiFe] hydrogenase
Hydrogenases are complex metalloenzymes that catalyze the reversible splitting of molecular hydrogen into protons and electrons essentially without overpotential. The NAD(+)-reducing soluble hydrogenase (SH) from Ralstonia eutropha is capable of H(2) conversion even in the presence of usually toxic...
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| Publicado en: | Chem Sci |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4321745/ https://ncbi.nlm.nih.gov/pubmed/25678951 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02982h |
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