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Identification of the dioxygenase-generated intermediate formed during biosynthesis of the dihydropyrrole moiety common to anthramycin and sibiromycin

A description of pyrrolo[1,4]benzodiazepine (PBD) biosynthesis is a prerequisite for engineering production of analogs with enhanced antitumor activity. Predicted dioxygenases Orf12 and SibV associated with dihydropyrrole biosynthesis in PBDs anthramycin and sibiromycin, respectively, were expressed...

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發表在:Bioorg Med Chem
Main Authors: Saha, Shalini, Li, Wei, Gerratana, Barbara, Rokita, Steven E.
格式: Artigo
語言:Inglês
出版: 2014
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4302019/
https://ncbi.nlm.nih.gov/pubmed/25564379
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bmc.2014.12.024
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