Resonant Inelastic X-ray Scattering on Ferrous and Ferric Bis-imidazole Porphyrin and Cytochrome c: Nature and Role of the Axial Methionine–Fe Bond

[Image: see text] Axial Cu–S(Met) bonds in electron transfer (ET) active sites are generally found to lower their reduction potentials. An axial S(Met) bond is also present in cytochrome c (cyt c) and is generally thought to increase the reduction potential. The highly covalent nature of the porphyr...

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Veröffentlicht in:J Am Chem Soc
Hauptverfasser: Kroll, Thomas, Hadt, Ryan G., Wilson, Samuel A., Lundberg, Marcus, Yan, James J., Weng, Tsu-Chien, Sokaras, Dimosthenis, Alonso-Mori, Roberto, Casa, Diego, Upton, Mary H., Hedman, Britt, Hodgson, Keith O., Solomon, Edward I.
Format: Artigo
Sprache:Inglês
Veröffentlicht: American Chemical Society 2014
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4291809/
https://ncbi.nlm.nih.gov/pubmed/25475739
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5100367
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