Short-lived metal-centered excited state initiates iron-methionine photodissociation in ferrous cytochrome c

The dynamics of photodissociation and recombination in heme proteins represent an archetypical photochemical reaction widely used to understand the interplay between chemical dynamics and reaction environment. We report a study of the photodissociation mechanism for the Fe(II)-S bond between the hem...

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Veröffentlicht in:Nat Commun
Hauptverfasser: Reinhard, Marco E., Mara, Michael W., Kroll, Thomas, Lim, Hyeongtaek, Hadt, Ryan G., Alonso-Mori, Roberto, Chollet, Matthieu, Glownia, James M., Nelson, Silke, Sokaras, Dimosthenis, Kunnus, Kristjan, Driel, Tim Brandt van, Hartsock, Robert W., Kjaer, Kasper S., Weninger, Clemens, Biasin, Elisa, Gee, Leland B., Hodgson, Keith O., Hedman, Britt, Bergmann, Uwe, Solomon, Edward I., Gaffney, Kelly J.
Format: Artigo
Sprache:Inglês
Veröffentlicht: Nature Publishing Group UK 2021
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7889893/
https://ncbi.nlm.nih.gov/pubmed/33597529
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-21423-w
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