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New strategies for natural products containing chroman spiroketals()

Two cycloaddition strategies are described that lead to various chroman spiroketals from assorted exocyclic enol ethers. Unlike conventional thermodynamic ketalization strategies, the stereochemical outcome for this approach is determined by a kinetic cycloaddition reaction. Thus, the stereochemical...

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Bibliographic Details
Published in:Pure Appl Chem
Main Authors: Green, Jason C., Burnett, G. Leslie, Pettus, Thomas R. R.
Format: Artigo
Language:Inglês
Published: 2012
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4280069/
https://ncbi.nlm.nih.gov/pubmed/25554712
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1351/PAC-CON-11-10-34
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