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New strategies for natural products containing chroman spiroketals()

Two cycloaddition strategies are described that lead to various chroman spiroketals from assorted exocyclic enol ethers. Unlike conventional thermodynamic ketalization strategies, the stereochemical outcome for this approach is determined by a kinetic cycloaddition reaction. Thus, the stereochemical...

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Detalhes bibliográficos
Publicado no:Pure Appl Chem
Main Authors: Green, Jason C., Burnett, G. Leslie, Pettus, Thomas R. R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4280069/
https://ncbi.nlm.nih.gov/pubmed/25554712
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1351/PAC-CON-11-10-34
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