A Catalytic, Enantioselective Formal Synthesis of (+)-Dichroanone and (+)-Taiwaniaquinone H

[Image: see text] A catalytic, enantioselective formal synthesis of (+)-dichroanone and (+)-taiwaniaquinone H is reported. The all-carbon quaternary stereocenter was constructed by asymmetric conjugate addition catalyzed by a palladium(II) (S)-tert-butylpyridinooxazoline complex. The unexpected form...

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Bibliographic Details
Published in:Org Lett
Main Authors: Shockley, Samantha E., Holder, Jeffrey C., Stoltz, Brian M.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2014
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4275150/
https://ncbi.nlm.nih.gov/pubmed/25489925
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol5031537
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