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Probing chirality fluctuations in molecules by nonlinear optical spectroscopy

Symmetry breaking caused by geometric fluctuations can enable processes that are otherwise forbidden. An example is a perylene bisimide dyad whose dipole moments are perpendicular to each other. Förster-type energy transfer is thus forbidden at the equilibrium geometry since the dipolar coupling van...

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Pubblicato in:J Chem Phys
Autori principali: Mann, N., Nalbach, P., Mukamel, S., Thorwart, M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Institute of Physics 2014
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4272380/
https://ncbi.nlm.nih.gov/pubmed/25527933
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4903858
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