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Probing chirality fluctuations in molecules by nonlinear optical spectroscopy
Symmetry breaking caused by geometric fluctuations can enable processes that are otherwise forbidden. An example is a perylene bisimide dyad whose dipole moments are perpendicular to each other. Förster-type energy transfer is thus forbidden at the equilibrium geometry since the dipolar coupling van...
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| Veröffentlicht in: | J Chem Phys |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American Institute of Physics
2014
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4272380/ https://ncbi.nlm.nih.gov/pubmed/25527933 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4903858 |
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