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Nitrite binding to globins: linkage isomerism, EPR silence and reductive chemistry
The nitrite adducts of globins can potentially bind via O- or N- linkage to the heme iron. We have used EPR (electron paramagnetic resonance) and DFT (density functional theory) to explore these binding modes to myoglobin and hemoglobin. We demonstrate that the nitrite adducts of both globins have d...
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| Publicado no: | Nitric Oxide |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Elsevier
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4256065/ https://ncbi.nlm.nih.gov/pubmed/25172022 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.niox.2014.08.007 |
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