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Enantioselective α-amination enabled by a BINAM-derived phase-transfer catalyst
Chiral anion phase-transfer of aryldiazonium cations was utilized to achieve highly enantioselective α-amination of carbonyl compounds. A broad scope of indanone- and benzosuberone-derived substrates was amenable to this strategy. Critical to obtaining high levels of enantioselectivity was the use o...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2015
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4251561/ https://ncbi.nlm.nih.gov/pubmed/25485073 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02494j |
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