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Multidimensional reaction rate theory with anisotropic diffusion

An analytical expression is derived for the rate constant that describes diffusive transitions between two deep wells of a multidimensional potential. The expression, in contrast to the Kramers-Langer formula for the rate constant, is valid even when the diffusion is highly anisotropic. Our approach...

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Bibliografiska uppgifter
I publikationen:J Chem Phys
Huvudupphovsmän: Berezhkovskii, Alexander M., Szabo, Attila, Greives, Nicholas, Zhou, Huan-Xiang
Materialtyp: Artigo
Språk:Inglês
Publicerad: American Institute of Physics 2014
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4247370/
https://ncbi.nlm.nih.gov/pubmed/25429932
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4902243
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