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Multidimensional reaction rate theory with anisotropic diffusion
An analytical expression is derived for the rate constant that describes diffusive transitions between two deep wells of a multidimensional potential. The expression, in contrast to the Kramers-Langer formula for the rate constant, is valid even when the diffusion is highly anisotropic. Our approach...
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| Publicado no: | J Chem Phys |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Institute of Physics
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4247370/ https://ncbi.nlm.nih.gov/pubmed/25429932 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4902243 |
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