Stable Silenolates and Brook-Type Silenes with Exocyclic Structures

[Image: see text] The first silenolates with exocyclic structures [(Me(3)Si)(2)Si(Si(2)Me(4))(2)SiC(R)O](−)K(+) (2a: R = 1-adamantyl; 2b: mesityl; 2c: o-tolyl) were synthesized by the reaction of the corresponding acylcyclohexasilanes 1a–c with KOtBu. NMR spectroscopy and single-crystal X-ray diffra...

पूर्ण विवरण

में बचाया:
ग्रंथसूची विवरण
में प्रकाशित:Organometallics
मुख्य लेखकों: Haas, Michael, Fischer, Roland, Flock, Michaela, Mueller, Stefan, Rausch, Martin, Saf, Robert, Torvisco, Ana, Stueger, Harald
स्वरूप: Artigo
भाषा:Inglês
प्रकाशित: American Chemical Society 2014
ऑनलाइन पहुंच:https://ncbi.nlm.nih.gov/pmc/articles/PMC4228504/
https://ncbi.nlm.nih.gov/pubmed/25400314
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om500935r
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