Photoinduced Brook-Type Rearrangement of Acylcyclopolysilanes

[Image: see text] Previously unknown 1,1,4-tris(trimethylsilyl)-4-acyldodecamethylcyclohexasilanes (Me(3)Si)(2)Si(6)Me(12)(Me(3)Si)COR (16a, R = tert-butyl; 16b, R = 1-adamantyl) have been synthesized by the reaction of the potassium silanides (Me(3)Si)(2)Si(6)Me(12)(Me(3)Si)K with acid chlorides Cl...

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Bibliografiske detaljer
Main Authors: Stueger, Harald, Hasken, Bernd, Haas, Michael, Rausch, Martin, Fischer, Roland, Torvisco, Ana
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2013
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3893937/
https://ncbi.nlm.nih.gov/pubmed/24465075
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om4009845
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