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Stable Silenolates and Brook-Type Silenes with Exocyclic Structures
[Image: see text] The first silenolates with exocyclic structures [(Me(3)Si)(2)Si(Si(2)Me(4))(2)SiC(R)O](−)K(+) (2a: R = 1-adamantyl; 2b: mesityl; 2c: o-tolyl) were synthesized by the reaction of the corresponding acylcyclohexasilanes 1a–c with KOtBu. NMR spectroscopy and single-crystal X-ray diffra...
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| Publicado no: | Organometallics |
|---|---|
| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4228504/ https://ncbi.nlm.nih.gov/pubmed/25400314 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om500935r |
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